Dehydration of 1,4-Butanediol to Tetrahydrofuran Catalyzed by H6P2W18O62/Diatomite

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Simulation of the Tetrahydrofuran Dehydration Process by Extractive Distillation

−− The aim of this work is to simulate and analyze an extractive distillation process (extractive distillation and recovery columns) for the separation of Tetrahydrofuran (THF)-Water azeotropic mixture using Aspen Plus® and Aspen Split simulators. Calculation of vapor liquid equilibrium of Tetrahydrofuran–Water–Entrainer system was done using the NRTL model, which binary interaction parameters ...

متن کامل

One-Step Production of 1,3-Butadiene from 2,3-Butanediol Dehydration.

We report the direct production of 1,3-butadiene from the dehydration of 2,3-butandiol by using alumina as catalyst. Under optimized kinetic reaction conditions, the production of methyl ethyl ketone and isobutyraldehyde, formed via the pinacol-pinacolone rearrangement, was markedly reduced and almost 80 % selectivity to 1,3-butadiene and 1,3-butadiene could be achieved. The presence of water p...

متن کامل

Simulation of the Tetrahydrofuran Dehydration Process by Extractive Distillation in Aspen Plus

The aim of this work is to simulate and analyze an extractive distillation process (extractive distillation and recovery columns) for the separation of Tetrahydrofuran(THF)-Water azeotropic mixture using Aspen Plus® and Aspen Split simulators. Calculation of vapor liquid equilibrium of Tetrahydrofuran–Water– Entrainer system was done using the NRTL model, which binary interaction parameters wer...

متن کامل

Dehydration of 2,3-butanediol to methyl ethyl ketone in sub- and supercritical water

Polyols can be synthesized from carbohydrates in bioor chemo-catalytic way. The conversion of polyols with two hydroxyl groups in 1,4-positions, for example 1,4-butanediol, results in furan derivatives. In contrast, during the dehydration of diols with two vicinal hydroxyl groups, for example, 1,2-propaneand 1,2-butanediol, aldehydes or ketones are formed [1] . This will be presented exemplaril...

متن کامل

Efficient Dehydration of Fructose to 5-Hydroxy- methylfurfural Catalyzed by Heteropolyacid Salts

5-Hydroxymethylfurfural (5-HMF), which is derived from numerous industrial biomass resources, has attracted attention in recent years due to its potential as a building block. In this paper, a range of heteropolyacid salts had been investigated for the dehydration of fructose to 5-HMF. CePW12O40 demonstrated the best catalytic activity. Effects of fructose concentration, reaction temperature an...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Chinese Journal of Organic Chemistry

سال: 2013

ISSN: 0253-2786

DOI: 10.6023/cjoc201210040